Effects of sintering atmospheres on thermoelectric properties, phase, microstructure and lattice parameters c/a ratio of Al, Ga dual doped ZnO ceramics sintered at high temperature
| Autor: | Arif Zaman, Jinze Zhai, D. K. Liu, Chengguo Wang, Ikram Ullah, Wenbin Su, Matiullah |
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| Rok vydání: | 2018 |
| Předmět: |
010302 applied physics
Argon Materials science Doping chemistry.chemical_element Sintering 02 engineering and technology 021001 nanoscience & nanotechnology Condensed Matter Physics Microstructure 01 natural sciences Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials chemistry Electrical resistivity and conductivity visual_art Seebeck coefficient 0103 physical sciences Thermoelectric effect visual_art.visual_art_medium Ceramic Electrical and Electronic Engineering Composite material 0210 nano-technology |
| Zdroj: | Journal of Materials Science: Materials in Electronics. 29:9555-9563 |
| ISSN: | 1573-482X 0957-4522 |
| DOI: | 10.1007/s10854-018-8990-7 |
| Popis: | Thermoelectric properties, phase and microstructural investigation of (Zn1−x−yAlxGay)O, where x = 0.02, y = 0.04, 0.05 and x = 0.03, y = 0.01, 0.02 are studied at a high temperature of 1450 °C in this article. We have focused on the effects of sintering atmospheres on thermoelectric properties, phase, and microstructure in the air as well in the argon atmosphere. The Seebeck coefficient (S) and electrical resistivities (ρ) measured in air and argon atmospheres have an evidential large difference. The air sintered Al, Ga co-doped ZnO has higher power factor (S2σ) of the order 720.9 µW K− 2 m− 1 and lower electrical resistivity (ρ) of 5.803 mΩ cm for the nominal formula (Zn1− x−yAlxGay)O, with x = 0.03, y = 0.01 as compared to the power factor 543.6 µW K− 2 m− 1 and electrical resistivity of the order 1.550 mΩ cm at 692.2 °C sintered in the argon atmosphere at the same temperature i.e. 1450 °C. The power factor of the air sintered sample with x = 0.03, y = 0.01 is 1.4 times higher than the argon sintered sample with the same composition. The difference in power factors and electrical resistivities are linked to sintering atmospheres. We will investigate the effects of sintering atmospheres of the co-doped ZnO and will study thermoelectric properties, phase, and microstructures of the co-doped ZnO. |
| Databáze: | OpenAIRE |
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