Parviflorine, a glycosidic spirobenzylisoquinoline alkaloid

Autor:	S. Fazal Hussain, Maurice Shamma
Rok vydání:	1980
Předmět:	chemistry.chemical_classification biology Stereochemistry Alkaloid Organic Chemistry Absolute configuration Fumaria parviflora Glycosidic bond biology.organism_classification Ring (chemistry) Biochemistry chemistry Drug Discovery Acid hydrolysis
Zdroj:	Tetrahedron Letters. 21:1909-1912
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)93641-4
Popis:	(+)-Parviflorine ( 1 ), found in Fumaria parviflora Lam. (Fumariaceae), is the first known glycosidic spirobenzylisoquinoline alkaloid. Its acid hydrolysis yields (+)-parfumine ( 4 ) and D-glucose. Klyne's rule indicates that 1 is a β-D-glucoside. The absolute configuration shown in expressions 1-11 is predominant among spirobenzylisoquinolines. A generalization has been drawn between plant source and the oxygenation pattern of ring C for the spirobenzylisoquinoline alkaloids.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::58a10ae36c2a59a76faea4b8de5eb68c https://doi.org/10.1016/s0040-4039(00)93641-4 Zobrazit plný text záznamu