O-Acylation of Substituted Phenols with Various Alkanoyl Chlorides Under Phase-Transfer Catalyst Conditions

Autor:	Naoyoshi Egashira, Iwao Hashimoto, Cristian Simion, Yoshiharu Mitoma, Alina Simion
Rok vydání:	2011
Předmět:	Hindered phenol O acylation chemistry.chemical_compound Aqueous solution chemistry Organic Chemistry Organic chemistry Phenols Phase-transfer catalyst Catalysis Dichloromethane Tetrabutylammonium chloride
Zdroj:	Synthetic Communications. 42:921-931
ISSN:	1532-2432 0039-7911
Popis:	Esterification of several types of mono- and disubstituted phenols with various mono- and dialkanoyl chlorides was performed in phase-transfer catalysis conditions, using tetrabutylammonium chloride in a mixture of aqueous NaOH and dichloromethane. The process is particularly efficient (almost quantitative yields) as well as rapid (only 5 min reaction time, at a temperature of 0 °C).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::589a8807704914d498dd04cfda12c1cc https://doi.org/10.1080/00397911.2011.584007 Zobrazit plný text záznamu