Reaction of trans-1,2-dichloroethylene with phosphorus trichloride–oxygen: the direct formation of a phosphate derivative from an olefin

Autor:	Clive B. C. Boyce, Shirley B. Webb
Rok vydání:	1971
Předmět:	Olefin fiber Trace Amounts Chemistry Phosphorus Organic Chemistry chemistry.chemical_element Phosphate Medicinal chemistry Oxygen chemistry.chemical_compound Yield (chemistry) Organic chemistry Phosphorus trichloride Derivative (chemistry)
Zdroj:	J. Chem. Soc. C. :1613-1615
ISSN:	0022-4952
DOI:	10.1039/j39710001613
Popis:	The reaction of trans-1,2-dichloroethylene with phosphorus trichloride–oxygen gives Cl2P(:O)·O·CHCl·CHCl2 as the major product (ca. 40% yield) and not the phosphonyl dichloride, Cl2P(:O)·CHCl·CHCl2, as previously reported. This is the first example of the direct formation of a phosphate derivative from an olefin. The phosphonyl dichloride is formed only in trace amounts together with two other minor products [Cl2P(:O)·CHCl2 and Cl2P(:O)·O·CHCl2] resulting from C–C cleavage of the olefin.
Databáze:	OpenAIRE
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