Synthesis and Characterization of Rhenium Thiolate Complexes. Crystal and Molecular Structures of [NBu4][ReO(H2O)Br4)]·2H2O, [Bu4N][ReOBr4(OPPh3)], [ReO(SC5H4N)3], [ReO(SC4H3N2)3][ReO(OH)(SC5H4N-3,6-(SiMe2But)2)2], [Re(N2COC6H5)(SC5H4N)Cl(PPh3)2], and [Re(PPh3)(SC4H3N2)3]

Autor:	Yuan Da Chang, David J. Rose, Kevin P. Maresca, Qin Chen, Abrams Michael J, Scott K. Larsen, Peter B. Kettler, Jon Zubieta, Victoria Soghomomian
Rok vydání:	1996
Předmět:	Inorganic Chemistry Crystal Tetragonal crystal system Crystallography chemistry.chemical_compound Trimethylsilyl Chemistry Crystal data chemistry.chemical_element Physical and Theoretical Chemistry Rhenium Triclinic crystal system Monoclinic crystal system
Zdroj:	Inorganic Chemistry. 35:3548-3558
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic950881o
Popis:	The syntheses and characterizations of six monomeric rhenium thiolate complexes and the structural characterization of two useful rhenium starting materials are presented. Pyridine-2-thiol (1) and its derivatives 3-(trimethylsilyl)pyridine-2-thiol (2), 3,6-bis(dimethyl-tert-butylsilyl)pyridine-2-thiol (3), and pyrimidine-2-thiol (4) were reacted with [Bu4N][ReOBr4(H2O)]·2H2O (5), [Bu4N][ReOBr4(OPPh3)] (6), [ReO2(C5H5N)4], and [Re{N2CO(C6H5)}Cl2(PPh3)2] to give [ReO(C5H4NS)3] (7), [ReO(C8H12NSiS)3] (8), [ReO(OH)(C11H20NSi2S)2] (9), [Re{N2CO(C6H5)}Cl(PPh3)2(C5H4NS)] (10), [ReO(C4H3N2S)3] (11), and [Re{P(C6H5)3}(C4H3N2S)3] (12). Crystal data: 5, C16H42NO4Br4Re, tetragonal, I4, a = 8.779(2) A, b = 11.614(2) A, c = 9.397(2) A, β = 114.67(3)°, V = 870.7(4) A3, Z = 2, 422 reflections, R = 0.0457; 6, C34H51NO2PBr4Re, triclinic, P1, a = 14.437(3) A, b = 16.589(3) A, c = 16.783(3) A, α = 94.87(3)°, β = 97.62(3)°, γ = 93.80(3)°, V = 3957(2) A3, Z = 4, 6141 reflections, R = 0.0758; 7, C15H12N3OS3Re, monoclinic, P2...
Databáze:	OpenAIRE
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