The study of phase behavior of aqueous 1-propanol/2-propanol/2-butanol/2-methyl-2-propanol systems in the presence of disodium tartrate or disodium succinate at T=298.15K

Autor:	Vahid Hosseinpour-Hashemi, Sepideh Banisaeid, Mohammad Ali Shamsi Beirami, Mohammed Taghi Zafarani-Moattar
Rok vydání:	2013
Předmět:	Binodal Aqueous solution General Chemical Engineering Inorganic chemistry General Physics and Astronomy Alcohol Tartrate Propanol chemistry.chemical_compound 1-Propanol chemistry Phase (matter) Physical and Theoretical Chemistry 2-Butanol Nuclear chemistry
Zdroj:	Fluid Phase Equilibria. 338:37-45
ISSN:	0378-3812
DOI:	10.1016/j.fluid.2012.10.019
Popis:	Liquid–liquid equilibria (LLE) of the 1-propanol/2-propanol/2-butanol/2-methyl-2-propanol + disodium tartrate or disodium succinate + water systems have been measured at T = 298.15 K. The Merchuk et al. equation was used to correlate the obtained binodal data. The effect of some factors such as length of alcohol chain, polarity of alcohol and the type of salt on the phase behavior of these systems has been discussed. In addition, the experimental tie-lines were reproduced using the Othmer–Tobias and Bancroft, Setschenow-type equations and the generalized electrolyte-NRTL and generalized Wilson models. Finally, the plait points of these investigated systems were estimated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5874173a12d21609127792c4bd97077b https://doi.org/10.1016/j.fluid.2012.10.019 Zobrazit plný text záznamu Full Text from ScienceDirect