The activity coefficient of high density systems with hard-sphere interactions: the application of the IGCMC method
| Autor: | Stanisław Lamperski, Monika Pluciennik |
|---|---|
| Rok vydání: | 2010 |
| Předmět: |
Activity coefficient
Chemistry General Chemical Engineering Monte Carlo method Binary number Inverse Thermodynamics General Chemistry Electrolyte Condensed Matter Physics Atomic packing factor Ion Condensed Matter::Soft Condensed Matter Modeling and Simulation Molecule General Materials Science Physics::Chemical Physics Information Systems |
| Zdroj: | Molecular Simulation. 36:111-117 |
| ISSN: | 1029-0435 0892-7022 |
| DOI: | 10.1080/08927020903124577 |
| Popis: | The inverse grand-canonical Monte Carlo (IGCMC) technique is used to calculate the activity coefficients of the following hard-sphere systems: one-component fluid, binary mixture and solvent primitive model (SPM) electrolyte. The calculations for a one-component fluid are performed at different densities. The components of a binary mixture differ in diameters (300 and 500 pm) with the results being presented for different density and composition of a mixture. For the SPM model, simulations are performed for a 1:1 electrolyte at different electrolyte concentrations at the packing fraction equal to 0.3. Ions and solvent molecules of the same or different sizes are considered. The results are compared with those reported by Adams (one-component fluid), with those calculated using the Ebeling and Scherwinski equation (one-component fluid and binary mixture) and with the predictions from the symmetric Poisson–Boltzmann theory and the mean spherical approximation (SPM electrolyte). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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