Base-Promoted Transmetalation Reactions of Protic N-Heterocyclic Carbenes and Acyclic Diamino Carbenes from MnI to AuI: A Mechanistic Study
| Autor: | Marilín Vivanco, Juan F. Van der Maelen, Javier Ruiz, Daniel Sol |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Reaction mechanism
010405 organic chemistry Chemistry Transition metal carbene complex Organic Chemistry chemistry.chemical_element Reaction intermediate Manganese 010402 general chemistry Photochemistry 01 natural sciences Medicinal chemistry Transition state 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Transmetalation Moiety Physical and Theoretical Chemistry Carbene |
| Zdroj: | Organometallics. 36:1035-1041 |
| ISSN: | 1520-6041 0276-7333 |
| Popis: | DFT theoretical calculations for the base-induced transmetalation process of protic N-heterocyclic carbenes of imidazol-2-ylidene type from Mn(I) to Au(I) have been carried out. The reaction mechanism found involves the formation of key reaction intermediates bearing a pure bridging imidazolyl ligand between manganese and gold, as well as transition states showing η2 coordination of this ligand, first to gold and then to manganese, before the transmetalation process is completed. In addition, similar DFT calculations have been performed on protic acyclic diamino carbene complexes, showing analogous transferring of the carbene moiety from Mn(I) to Au(I) to afford remarkable mangana-N-heterocyclic carbenes of gold. |
| Databáze: | OpenAIRE |
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