ChemInform Abstract: Flexible Synthesis of Vulpinic Acids from Tetronic Acid

Autor:	Charles Mioskowski, Celia Billaud, Catherine Willis, Thierry Le Gall, Yann Bourdreux, Ewen Bodio
Rok vydání:	2008
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Vulpinic acid Chemistry Iodide Pinastric acid Organic chemistry General Medicine Tetronic acid
Zdroj:	ChemInform. 39
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200801092
Popis:	Several vulpinic acids were synthesized in a few steps from a single precursor, the tetronic acid. This commercial compound was converted in a few steps to an iodide. Suzuki–Miyaura cross-couplings involving this common intermediate and various arylboronates allowed to gain access to several vulpinic acids (or methyl pulvinates). Among them, two natural products, vulpinic acid and pinastric acid, were prepared.
Databáze:	OpenAIRE
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