5-Diisopropoxyphosphoryl-5-methyl-1-pyrroline N-oxide, DIPPMPO, a crystalline analog of the nitrone DEPMPO: synthesis and spin trapping propertiesElectronic supplementary information (ESI) available: Tables of crystallographic data. See http://www.rsc.org/suppdata/p2/b2/b206909c

Autor:	Florence Chalier, Paul Tordo
Rok vydání:	2002
Předmět:	chemistry.chemical_classification Spin trapping Chemistry Radical Phosphate buffered saline Oxide Pyrroline Nitrone law.invention chemistry.chemical_compound law Polymer chemistry Organic chemistry Electron paramagnetic resonance
Zdroj:	Journal of the Chemical Society, Perkin Transactions 2. :2110-2117
ISSN:	1364-5471 1472-779X
DOI:	10.1039/b206909c
Popis:	The nitrone DIPPMPO (5-diisopropoxyphosphoryl-5-methyl-1-pyrroline N-oxide) was synthesised, isolated as hygroscopic crystals and its X-ray geometry was determined. The purification of DIPPMPO was easy, compared with that of DEPMPO (5-diethoxyphosphoryl-5-methyl-1-pyrroline N-oxide) and its solutions in phosphate buffer were EPR silent. DIPPMPO exhibits all the advantages of DEPMPO for the spin-trapping of biological free radicals and thus DIPPMPO is a choice tool in this field.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5825b084d815bd00799e3d0f7f975176 https://doi.org/10.1039/b206909c Zobrazit plný text záznamu