Controlled deactivation of a skeletal nickel catalyst with sodium silfide in liquid-phase hydrogenation reactions

Autor:	D. A. Prozorov, Yu. A. Vdovin, M. V. Lukin, M. V. Ulitin
Rok vydání:	2013
Předmět:	inorganic chemicals Sodium Inorganic chemistry Kinetics chemistry.chemical_element Liquid phase General Chemistry Catalysis Sodium sulfide Computer Science Applications Nickel chemistry.chemical_compound chemistry Modeling and Simulation Nickel catalyst Sodium maleate
Zdroj:	Kinetics and Catalysis. 54:412-419
ISSN:	1608-3210 0023-1584
DOI:	10.1134/s0023158413040101
Popis:	The kinetics of the liquid-phase hydrogenation of sodium maleate on skeletal nickel catalysts subjected to controlled deactivation with sodium sulfide solutions was studied. The possibility of reactivating partially deactivated skeletal nickel was systematically studied for the first time, and it was found that its activity in liquid-phase hydrogenation reactions can be regulated by the introduction of a catalyst poison in small amounts into the system.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::580823746c6ef860ffd059cf3209b611 https://doi.org/10.1134/s0023158413040101 Zobrazit plný text záznamu Plný text ve formátu PDF