Mass-spectrometric investigation of isatins

Autor:	G. I. Zhungietu, Kh. Sh. Khariton, B. T. Oloi, M. A. Rekhter, N. I. Chmykhova
Rok vydání:	1975
Předmět:	chemistry.chemical_classification Hydrogen Chemistry Isatin Organic Chemistry Polyatomic ion chemistry.chemical_element Hydrogen atom Photochemistry Spectral line Crystallography chemistry.chemical_compound Atom Mass spectrum Alkyl
Zdroj:	Chemistry of Heterocyclic Compounds. 11:840-843
ISSN:	1573-8353 0009-3122
Popis:	It is shown that in the mass spectra of N-alkylisatins with a normal C1-C10 chain the intensity of the [M-CO]+- and [M-(2CO)]+. peaks characteristic for isatin and N-methylisatin decreases as the alkyl radical is lengthened, whereas the intensity of the peak formed as a result of successive loss by the molecular ion of a CO group and a portion of the radical as a result of cleavage of the bond at the α-carbon atom increases. Fragments due to α,β,γ... cleavages, both without migration and with migration of the hydrogen atoms, appear in the spectra of N-alkylisatins commencing with chains containing more than two C atoms.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::57fba046c628c982252441b26bdb63c6 https://doi.org/10.1007/bf00497309 Zobrazit plný text záznamu Full text from SpringerLink