Electrochemical synthesis and spectroscopic characterization of a mercury–platinum–hydride complex
| Autor: | Cassandra T. Eagle, David G. Farrar, Pannee Burckel, Julian A. Davies |
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| Rok vydání: | 2000 |
| Předmět: |
Electrolysis
Chemistry Hydride Analytical chemistry chemistry.chemical_element Nuclear magnetic resonance spectroscopy Electrochemistry law.invention Inorganic Chemistry NMR spectra database law Inductively coupled plasma atomic emission spectroscopy Materials Chemistry Physical and Theoretical Chemistry Spectroscopy Platinum |
| Zdroj: | Inorganica Chimica Acta. :645-652 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/s0020-1693(00)00023-2 |
| Popis: | Controlled potential bulk reductive electrolysis of trans -[PtI 2 (PEt 3 ) 2 ] in 5:2 C 6 H 5 CN:C 6 H 6 (saturated with NaClO 4 ) at a Hg pool electrode at −1.5 V (vs. Ag/AgCl) and at approximately 0°C, yielded two compounds detectable by 31 P{ 1 H} NMR spectroscopy. One compound was the starting material, trans -[PtI 2 (PEt 3 ) 2 ], while the other displayed a complex spectrum. Analysis of the 1 H, 31 P{ 1 H} and 195 Pt{ 1 H} NMR spectra suggested that the compound contained an unaccounted for spin one-half nucleus. Scanning electron microscopy–energy dispersive spectroscopy and inductively coupled plasma atomic emission spectroscopy indicated that the compound contained mercury and the spectra could be satisfactorily interpreted in terms of a mercury–platinum–hydride structure. |
| Databáze: | OpenAIRE |
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