ChemInform Abstract: Asymmetric Induction in Stereoselective Carbocyclization of Cyclohexanone Enamines

Autor:	Arvydas Stoncius, Eugenius Butkus
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Reaction mechanism chemistry.chemical_compound Bicyclic molecule chemistry Enantioselective synthesis Organic chemistry Cyclohexanone Stereoselectivity General Medicine Nonane Bridged compounds Asymmetric induction
Zdroj:	ChemInform. 30
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.199924076
Popis:	A highly enantioselective synthesis of bicyclo[3.3.1]nonane diketones 3-5 was accomplished by (S)and (R)-2methoxymethylpyrrolidine induced asymmetric cyclization of cyclohexanone enamines 1,2 in reaction with propenoyl chloride. A possible enantiodifferentiation reaction mechanism was suggested.
Databáze:	OpenAIRE
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