Tetramethylammonium trifluoromethyltellurate(0), [NMe4]TeCF3, synthesis, characterisation and properties

Autor:	Nataliya V. Kirij, Wieland Tyrra, Dieter Naumann, Yurii L. Yagupolskii
Rok vydání:	2004
Předmět:	Tetramethylammonium Organic Chemistry Inorganic chemistry chemistry.chemical_element Biochemistry Medicinal chemistry Ion Inorganic Chemistry chemistry.chemical_compound chemistry Nucleophile Yield (chemistry) Environmental Chemistry Ammonium Physical and Theoretical Chemistry Tellurium
Zdroj:	Journal of Fluorine Chemistry. 125:1437-1440
ISSN:	0022-1139
Popis:	[NMe 4 ]TeCF 3 is obtained in 60% yield from Me 3 SiCF 3 , elemental tellurium and [NMe 4 ]F in glyme as a pale yellow solid decomposing at 185 °C. Cation exchange with [PNP]Br ([PNP] = bis(triphenylphosphoranylidene)ammonium) and [(dibenzo-18-crown-6)K]Br occurs spontaneously. These low co-ordinating cations increase significantly the nucleophilicity of the anion.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::57dbfca05ec3fa5a7638dc7dc7668ccc https://doi.org/10.1016/j.jfluchem.2004.04.012 Zobrazit plný text záznamu Full Text from ScienceDirect