Modification of the van der Waals interaction at the Bi2Te3 and Ge(111) interface

Autor: Kenji Nawa, Balati Kuerbanjiang, Susannah Speller, Vlado K. Lazarov, Guillermo Bárcena-González, Demie Kepaptsoglou, Quentin M. Ramasse, Giuseppe Nicotra, Pedro L. Galindo, Thorsten Hesjedal, Kohji Nakamura, Arsham Ghasemi, P. J. Hasnip
Rok vydání: 2021
Předmět:
Zdroj: Physical Review Materials. 5
ISSN: 2475-9953
DOI: 10.1103/physrevmaterials.5.024203
Popis: We present a structural and density-functional theory study of the interface of the quasi-twin-free grown three-dimensional topological insulator Bi2Te3 on Ge(111). Aberration-corrected scanning transmission electron microscopy and electron energy-loss spectroscopy in combination with first-principles calculations show that the weak van der Waals adhesion between the Bi2Te3 quintuple layer and Ge can be overcome by forming an additional Te layer at their interface. The first-principles calculations of the formation energy of the additional Te layer show it to be energetically favorable as a result of the strong hybridization between the Te and Ge.
Databáze: OpenAIRE