Chemical Etching of Si1 − x Ge x in HF : H 2 O 2 : CH 3 COOH

Autor: Kang L. Wang, T. K. Cams, M. O. Tanner
Rok vydání: 1995
Předmět:
Zdroj: Journal of The Electrochemical Society. 142:1260-1266
ISSN: 1945-7111
0013-4651
DOI: 10.1149/1.2044161
Popis: The properties of a highly selective chemical etchant composed of hydrofluoric acid, hydrogen peroxide, and acetic acid (HF:H 2 O 2 :CH 3 COOH) is investigated in etching SiGe/Si heterostructures. This solution has been found to etch Si 1-x Ge x much faster than Si over the entire range of Ge contents. The etch rate dependences are presented as functions of solution composition, Ge content, dopant type, diluent type, temperature, and stirring. Both n-type and p-type Si 1-x Ge x layers with Ge contents of 0≤x≤0.60 and 0≤x≤1.00, respectively, are investigated. It is found that the n-type samples etch at a faster rate than p-type for all Ge contents examined. When CH 3 COOH is used as the diluent instead of H 2 O a significant enhancement in the etch rate results for all concentrations of Ge studied. Also, the amount of H 2 O 2 in the presence of CH 3 COOH has a significant effect on the magnitude of the etch rate as well as its behavior over time
Databáze: OpenAIRE