Kinetics of the reaction of diphenyl chlorophosphate with the 4-nitrophenolate ion under inverse phase transfer catalysis conditions

Autor:	V. N. Anishchenko, A. N. Red’ko, K. Yu. Chotii, V. I. Rybachenko
Rok vydání:	2012
Předmět:	chemistry.chemical_compound chemistry Phase (matter) Kinetics Pyridine Proton NMR Infrared spectroscopy Ionic bonding General Chemistry Photochemistry Ion Catalysis
Zdroj:	Theoretical and Experimental Chemistry. 48:172-175
ISSN:	1573-935X 0040-5760
DOI:	10.1007/s11237-012-9257-7
Popis:	The reaction of diphenyl chlorophosphate with the 4-nitrophenolate ion was studied in the presence of a series of para derivatives of pyridine 1-oxide under inverse phase transfer catalysis (IPTC) conditions. The reaction proceeds due to the formation of an ionic intermediate in the organic phase, namely, 1-(diphenoxyphosphoryl) oxypyridinium salts. This conclusion was indicated by both 1H NMR and IR spectroscopy.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::57ac2f8299040d7f8fece744c2ffd7f1 https://doi.org/10.1007/s11237-012-9257-7 Zobrazit plný text záznamu Plný text ve formátu PDF