Modification of Mg2Si in Mg–Si alloys with gadolinium

Autor: Zhaoyang Liu, Xinming Zhang, Jilong Hu, Zhile Zhou, Yunlai Deng, Lingying Ye, Tang Changping
Rok vydání: 2013
Předmět:
Zdroj: Materials Characterization. 79:1-6
ISSN: 1044-5803
DOI: 10.1016/j.matchar.2013.02.005
Popis: The modification effect of gadolinium (Gd) on Mg 2 Si in the hypereutectic Mg–3 wt.% Si alloy has been investigated using optical microscope, scanning electron microscope, X-ray diffraction and hardness measurements. The results indicate that the morphology of the primary Mg 2 Si is changed from coarse dendrite into fine polygon with the increasing Gd content. The average size of the primary Mg 2 Si significantly decreases with increasing Gd content up to 1.0 wt.%, and then slowly increases. Interestingly, when the Gd content is increased to 4.0 and 8.0 wt.%, the primary and eutectic Mg 2 Si evidently decrease and even disappear. The modification and refinement of the primary Mg 2 Si is mainly attributed to the poisoning effect. The GdMg 2 phase in the primary Mg 2 Si is obviously coarsened as the Gd content exceeds 2.0 wt.%. While the decrease and disappearance of the primary and eutectic Mg 2 Si are ascribed to the formation of vast GdSi compound. Therefore, it is reasonable to conclude that proper Gd (1.0 wt.%) addition can effectively modify and refine the primary Mg 2 Si.
Databáze: OpenAIRE