Applications of electrochemical ferrate(VI) for degradation of trichloroethylene in the aqueous phase
| Autor: | Jae Hyun Kwon, Young Do Kim, Joo-Hee Nam, Il-Kyu Kim |
|---|---|
| Rok vydání: | 2015 |
| Předmět: |
Aqueous solution
Chloroform Trichloroethylene Ethyl Chloride Inorganic chemistry Aqueous two-phase system Ocean Engineering 02 engineering and technology 010501 environmental sciences 021001 nanoscience & nanotechnology 01 natural sciences Pollution chemistry.chemical_compound chemistry Degradation (geology) 0210 nano-technology Ferrate(VI) Trichloroethane 0105 earth and related environmental sciences Water Science and Technology |
| Zdroj: | Desalination and Water Treatment. 57:5138-5145 |
| ISSN: | 1944-3986 1944-3994 |
| DOI: | 10.1080/19443994.2014.1001440 |
| Popis: | The degradation of trichloroethylene (TCE) by ferrate generated from electrochemical synthesis has been studied. The degradation efficiency of TCE in aqueous solution was observed at various pH (3, 7, 11), ferrate dosages (5, 8, 11, 13, 15 and 17 mg/L), and temperature (10, 25, 35 and 50°C). The experimental results showed that TCE removal efficiency increased with an increase in ferrate dosages. For the effect of pH, the highest value of kapp, 893.54 M−1s−1, was observed at pH 7. The TCE degradation pathways have been proposed based on the intermediate products such as ethyl chloride, dichloroethylene, chloroform, 1,1-dichloropropene, trichloroacetic acid and trichloroethane, and Cl− was identified as an end product. |
| Databáze: | OpenAIRE |
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