Alternation between modes of electron transmission through organized organic layers
Autor: | Zeev Vager, Ron Naaman, Itai Carmeli, Ziv Gefen |
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Rok vydání: | 2003 |
Předmět: | |
Zdroj: | Physical Review B. 68 |
ISSN: | 1095-3795 0163-1829 |
DOI: | 10.1103/physrevb.68.115418 |
Popis: | Photoelectrons from gold covered with self-assembled monolayers of L-polyalanine were measured as a function of temperature. Spectra and asymmetries to circularly polarized light were recorded while monitoring the electric potential across the monolayer. Upon cooling, this potential changes gradually, passing through zero at 264 K. But, contrary to the gradual potential change, both the shape of spectra and the polarization asymmetry change abruptly at the edges of the temperature range Δ=264′ 10 K. Above and below A, opposite asymmetries are observed and the spectra are broad. Within Δ, a series of several sharp resonances appear with null asymmetry. |
Databáze: | OpenAIRE |
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