Line broadening of level crossing resonance spectra of muonated free radicals

Autor: David C. Walker, Krishnan Venkateswaran, Mary Vijayarani Barnabas
Rok vydání: 1990
Předmět:
Zdroj: The Journal of Physical Chemistry. 94:178-180
ISSN: 1541-5740
0022-3654
DOI: 10.1021/j100364a027
Popis: Ratios of the observed-to-theoretical line widths (squared) have been found to vary from 1.1 to 5.0 for the range of level crossing resonance data available for muonated free radicals. However, in each case there is an equal decrease in the observed-to-theoretical amplitude, so that the observed product (ampl)({Delta}B){sup 2} can be used to evaluate radical yields. Intrinsic line broadening evidently arises from several sources.
Databáze: OpenAIRE