Line broadening of level crossing resonance spectra of muonated free radicals
Autor: | David C. Walker, Krishnan Venkateswaran, Mary Vijayarani Barnabas |
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Rok vydání: | 1990 |
Předmět: | |
Zdroj: | The Journal of Physical Chemistry. 94:178-180 |
ISSN: | 1541-5740 0022-3654 |
DOI: | 10.1021/j100364a027 |
Popis: | Ratios of the observed-to-theoretical line widths (squared) have been found to vary from 1.1 to 5.0 for the range of level crossing resonance data available for muonated free radicals. However, in each case there is an equal decrease in the observed-to-theoretical amplitude, so that the observed product (ampl)({Delta}B){sup 2} can be used to evaluate radical yields. Intrinsic line broadening evidently arises from several sources. |
Databáze: | OpenAIRE |
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