Vanadium complexes immobilized on solid supports and their use as catalysts for oxidation and functionalization of alkanes and alkenes

Autor:	J. Costa Pessoa, Mannar R. Maurya, Amit Kumar
Rok vydání:	2011
Předmět:	Ion exchange Chemistry Vanadium chemistry.chemical_element Catalysis Inorganic Chemistry Adsorption MCM-41 Covalent bond Polymer chemistry Materials Chemistry Surface modification Organic chemistry Physical and Theoretical Chemistry Mesoporous material
Zdroj:	Coordination Chemistry Reviews. 255:2315-2344
ISSN:	0010-8545
DOI:	10.1016/j.ccr.2011.01.050
Popis:	This review mainly discusses the immobilization strategies that have been used for vanadium complexes, typically mesoporous material, zeolites and polymers, the characterization procedures for the obtained materials, and their catalytic applications. The retention of the active metal compound within the catalyst may be based on (i) adsorption, (ii) the formation of covalent bonds between metal ligand and support, (iii) ion exchange, (iv) encapsulation, or (v) entrapment. The heterogenized complexes are used as catalysts for oxidations and functionalization of alkanes, alkenes and other substrates, and an account of the various applications reported is given.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::56e324db5d28f0f584364598becb876c https://doi.org/10.1016/j.ccr.2011.01.050 Zobrazit plný text záznamu Full Text from ScienceDirect