Autor:	Yu. E. Shapiro, I. I. Seifullina, Alexander V. Mazepa, S. V. Zubkov, V. Ya. Gorbatyuk
Rok vydání:	2001
Předmět:	General Chemical Engineering Potassium Inorganic chemistry chemistry.chemical_element General Chemistry Electronic structure Ion chemistry.chemical_compound Nickel chemistry Salicylaldehyde Polymer chemistry Chelation Redistribution (chemistry) Benzene
Zdroj:	Russian Journal of Coordination Chemistry. 27:61-64
ISSN:	1070-3284
DOI:	10.1023/a:1009597010314
Popis:	The properties of complex compounds produced by template condensation of salicylideneaminoguanidines with salicylaldehyde on a nickel(II) ion matrix are studied. It is shown that the potassium ion in a nitrogen-substituted triazacyclic complex can be replaced by a tetrabutylammonium cation. The electronic structure of the compounds obtained is characterized using UV, IR, and (1H, 13C) NMR spectroscopies. A chelate compound produced from nitroaminoguanidine was found to exhibit the effect of electron density redistribution involving nickel AO. As a result, two benzene rings of the complex anion become nonequivalent.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::56d90c63de486743949c1ca69127006c https://doi.org/10.1023/a:1009597010314 Zobrazit plný text záznamu Full text from SpringerLink