First high resolution analysis of the ν3 band of the 36SF6 isotopologue
Autor: | Vincent Boudon, Michel Loete, Laurent Manceron, Mbaye Faye, Pascal Roy |
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Rok vydání: | 2018 |
Předmět: |
Physics
High resolution analysis 010304 chemical physics 010504 meteorology & atmospheric sciences Fourier transform spectrometers 01 natural sciences Atomic and Molecular Physics and Optics Computational physics symbols.namesake Formalism (philosophy of mathematics) 0103 physical sciences symbols Isotopologue Physical and Theoretical Chemistry Hamiltonian (quantum mechanics) Doppler effect Spectroscopy 0105 earth and related environmental sciences |
Zdroj: | Journal of Molecular Spectroscopy. 346:23-26 |
ISSN: | 0022-2852 |
Popis: | The ν 3 band of the 36 SF 6 isotopologue has been recorded in natural abundance (0.02%) at 153 K-temperature with doppler limited resolution, using a Fourier transform spectrometer. For the first time, the high resolution analysis of this band is performed thanks to the Dijon tensorial formalism model. The effective Hamiltonian parameters are determined and the interest of studying rare SF 6 isotopologues is discussed. |
Databáze: | OpenAIRE |
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