Synthesis, characterization and crystal structure of catena-bis(1,10-phenanthroline)-μ-chloranilatocadmium(II): a zig-zag polymer based on eight-coordinated square antiprismatic units
| Autor: | Stavroula Skoulika, Adonis Michaelides, Panagiotis Veltsistas, John C. Plakatouras, Christos Papadimitriou |
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| Rok vydání: | 2004 |
| Předmět: |
chemistry.chemical_classification
Thermogravimetric analysis Square antiprismatic molecular geometry Chemistry Phenanthroline Crystal structure Polymer Square antiprism Inorganic Chemistry Crystal symbols.namesake chemistry.chemical_compound Crystallography Materials Chemistry symbols Physical and Theoretical Chemistry Raman spectroscopy |
| Zdroj: | Polyhedron. 23:2587-2593 |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/j.poly.2004.09.013 |
| Popis: | [Cd(phen)2(CA)]n (I, where phen is 1,10-phenanthroline and CA2− is the dianion of 3,6-dichloro-2,5-dihydroxy-1,4-benzoquinone) has been synthesized and its crystal structure has been determined by single-crystal X-ray diffraction at room temperature. The crystal of I is built from infinite chains of chloranilate-bridged cadmium(II) leading to a zig-zag structure, with the phenanthroline ligands being stacked between the chains. These interactions assist the formation of a closely packed 3D structure. The coordination environment of cadmium(II) – very scarce in its chemistry – is square antiprismatic. The polymer was also characterized with spectroscopic (IR, Raman, DRS) and thermogravimetric (TG, DTA) techniques. |
| Databáze: | OpenAIRE |
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