Supramolecular porphyrin-based metal–organic frameworks: Cu(ii ) naphthoate–Cu(ii ) tetrapyridyl porphine structures exhibiting selective CO2/N2 separation
| Autor: | Tsuyoshi Matsumoto, Kazuyuki Tatsumi, Tetsushi Ohmura, Shunsuke Senda, Arimitsu Usuki, Yusuke Mukae, Norihiko Setoyama |
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| Rok vydání: | 2017 |
| Předmět: |
Inorganic chemistry
Supramolecular chemistry chemistry.chemical_element Sorption 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Porphyrin Copper 0104 chemical sciences chemistry.chemical_compound chemistry General Materials Science Metal-organic framework 0210 nano-technology |
| Zdroj: | CrystEngComm. 19:5173-5177 |
| ISSN: | 1466-8033 |
| DOI: | 10.1039/c7ce01138e |
| Popis: | 1 and 2 were synthesized through the complexation of 5,10,15,20-tetra-4-pyridyl-21H,23H-porphine with copper(II) acetate and copper(II) 1-naphthoate and exhibited two-dimensional open and closed form structures, respectively. X-ray diffraction identified the supramolecular interactions leading to these packing motifs. N2 and CO2 sorption isotherms indicate that 2 allows the separation of these gases. |
| Databáze: | OpenAIRE |
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