Triazine-based 2D covalent organic framework-derived nitrogen-doped porous carbon for supercapacitor electrode
| Autor: | Muthu Dinesh, Stella Vargheese, Yuvaraj Haldorai, K. V. Kavya, Ramasamy Thangavelu Rajendra Kumar, Dhanaprabhu Pattappan |
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| Rok vydání: | 2020 |
| Předmět: |
Supercapacitor
Materials science Renewable Energy Sustainability and the Environment Carbonization Process Chemistry and Technology Organic Chemistry Energy Engineering and Power Technology 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences Capacitance 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound chemistry Chemical engineering Materials Chemistry Ceramics and Composites Wetting 0210 nano-technology Porosity Covalent organic framework Triazine |
| Zdroj: | Carbon Letters. 31:879-886 |
| ISSN: | 2233-4998 1976-4251 |
| DOI: | 10.1007/s42823-020-00190-6 |
| Popis: | Doped porous carbon materials have attracted great interest owing to their excellent electrochemical performance toward energy storage applications. In this report, we described the synthesis of nitrogen-doped porous carbon (N-PC) via carbonization of a triazine-based covalent organic framework (COF) synthesized by Friedel–Crafts reaction. The as-synthesized COF and N-PC were confirmed by X-ray diffraction. The N-PC exhibited many merits including high surface area (711 m2 g−1), porosity, uniform pore size, and surface wettability due to the heteroatom-containing lone pair of electron. The N-PC showed a high specific capacitance of 112 F g−1 at a current density of 1.0 A g−1 and excellent cyclic stability with 10.6% capacitance loss after 5000 cycles at a current density of 2.0 A g−1. These results revealed that the COF materials are desirable for future research on energy storage devices. |
| Databáze: | OpenAIRE |
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