ChemInform Abstract: Truly Catalytic and Chemoselective Cleavage of Benzylidene Acetal with Phosphomolybdic Acid Supported on Silica Gel

Autor:	Ponminor Senthil Kumar, Gaddale Devanna Kishore Kumar, Sundarababu Baskaran
Rok vydání:	2009
Předmět:	Reaction conditions chemistry.chemical_compound chemistry Silica gel Polymer chemistry Acetal Phosphomolybdic acid Ether General Medicine Cleavage (embryo) Catalytic method Catalysis
Zdroj:	ChemInform. 40
ISSN:	1522-2667 0931-7597
Popis:	Phosphomolybdic acid supported on silica gel provides a truly catalytic method for the chemoselective cleavage of benzylidene acetals having sensitive functional groups under mild conditions. It is easy to perform on large scale owing to minimal catalyst loading (0.5 mol-%). Several sensitive functional groups such as TBDPS ether, -OMs, -OAc, allyl ether, N-Boc, N-Fmoc and N-Cbz are stable under the reaction conditions. In addition, benzylidene acetal is selectively cleaved in the presence of isopropylidene ketal.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::567c826425d7ab8d0a71b6f83b173f28 https://doi.org/10.1002/chin.200919048 Zobrazit plný text záznamu Plný text