Crystal structure and magnetic properties of binuclear copper(II) complex with 2-N-(phenylhydrazono)-3-((ethyl-2-olato)imino)-1-phenyl-1,2,3-butanetrione
| Autor: | Gennady V. Shilov, E. V. Ivannikova, Valery V. Tkachev, Vladimir V. Lukov, Leonid D. Popov, Igor N. Shcherbakov, V. A. Kogan, Yu. P. Tupolova, D. S. Samorodnyaya, Sergey I. Levchenkov |
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| Rok vydání: | 2016 |
| Předmět: |
Chemistry
Stereochemistry General Chemical Engineering Condensation chemistry.chemical_element General Chemistry Crystal structure 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Copper 0104 chemical sciences Magnetic exchange chemistry.chemical_compound Crystallography Pyridine Molecule Axial symmetry |
| Zdroj: | Russian Journal of Coordination Chemistry. 42:81-84 |
| ISSN: | 1608-3318 1070-3284 |
| Popis: | The binuclear copper(II) complex based on azomethine, being a condensation product of 2-aminoethanol with 1-phenyl-1,2,3-butanetrione phenylhydrazone, is structurally characterized (CIF file CCDC 1059996). The structure is compared with the structure of an analog containing the axially coordinated pyridine molecule. The influence of the axial coordination of pyridine on the magnetic exchange interaction is studied by the DFT method in the broken symmetry approach. |
| Databáze: | OpenAIRE |
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