Strong isotope effect on the intermolecular exchange integral of excited triplet-state dimers

Autor:	T.E. Altman, W.G. Breiland, J.S. Voris
Rok vydání:	1979
Předmět:	Chemistry Yield (chemistry) Excited state Exciton Intermolecular force Kinetic isotope effect General Physics and Astronomy Resonance Exchange matrix Physical and Theoretical Chemistry Triplet state Atomic physics
Zdroj:	Chemical Physics Letters. 67:30-35
ISSN:	0009-2614
DOI:	10.1016/0009-2614(79)87100-6
Popis:	High-resolution phosphorescence—microwave double resonance (PMDR) and optically detected magnetic resonance techniques have yielded two independent measurements of the nearest-neighbor excited-state exchange matrix element in dimers of 1,2,4,5-tetrachlorobenzene. Both experiments yield a value (0.07 cm −1 ) smaller than the value reported for exciton systems (0.34 cm −1 ), indicating a strong violation of the ideal mixed crystal concept.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::56701da1dc04deb993c900a76f1d89a1 https://doi.org/10.1016/0009-2614(79)87100-6 Zobrazit plný text záznamu