Single-crystal growth and structure determination of Ag16I12P2O7

Autor:	R. Faggiani, I.D. Brown, John E. Greedan, S. Carbotte, J.D. Garrett
Rok vydání:	1982
Předmět:	Diffraction Single crystal growth Chemistry Condensed Matter Physics Thermal conduction Electronic Optical and Magnetic Materials Conductor Ion Inorganic Chemistry Crystallography Polyhedron Materials Chemistry Ceramics and Composites Physical and Theoretical Chemistry
Zdroj:	Journal of Solid State Chemistry. 42:183-190
ISSN:	0022-4596
Popis:	Single crystals of the fast-ion conductor Ag16I12P2O7 were prepared and their structure ( P6 mcc , a = 12.054, c = 7.504 A) was determined by X-ray diffraction (r = 0.08). The I atoms form a close-packed array leaving channels occupied by P2O4−7 ions running along the c axis. The Ag atoms are disordered over four different types of site with occupation numbers ranging from 0.12 to 0.52. Each Ag+ ion coordination polyhedron shares several faces with adjacent polyhedra providing ready paths for Ag+ ion conduction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::566c77e59f47092ef5aadc77e7cb68c8 https://doi.org/10.1016/0022-4596(82)90266-3 Zobrazit plný text záznamu