Orthoamide und Iminiumsalze, LXXXIV [1]. Die Synthese von starken Formylierungsmitteln im präparativen Großmaßstab: Tris(dichlormethyl)amin / Orthoamides and Iminiumsalts LXXXIV [1]. The Synthesis of Strong Formylating Reagents on a Large Preparative Scale: Tris(chloromethyl)amine

Autor:	Ivo C. Ivanov, Georg Ziegler, Jochen Mezger, Oliver Scherr, Michael Csiesielski, Alain Goeppert, Markus Wezstein, Sylvia Leonhardt, Willi Kantlehner
Rok vydání:	2014
Předmět:	Tris chemistry.chemical_compound Chemistry Reagent Organic chemistry Amine gas treating General Chemistry Medicinal chemistry
Zdroj:	Zeitschrift für Naturforschung B. 69:525-532
ISSN:	1865-7117 0932-0776
DOI:	10.5560/znb.2014-3270
Popis:	Tris(chloromethyl)amine (4) can be prepared by chloromethylation of urotropin with paraformaldehyde or 1,3,5-trioxane and ethyl-trichlorosilane in good yields. Photochlorination of tris(chloromethyl)amine affords tris(dichloromethyl)amine (2). Both reactions can be performed on large scale.
Databáze:	OpenAIRE
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