Efficient removal of anti-inflammatory phenylbutazone from an aqueous solution employing a composite material based on poly(aniline-co-pyrrole)/multi-walled carbon nanotubes
| Autor: | Tienne Aparecida Do Nascimento, Keyller Bastos Borges, Bruna Carneiro Pires, Flávia Viana Avelar Dutra |
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| Rok vydání: | 2018 |
| Předmět: |
Aqueous solution
Aqueous two-phase system 02 engineering and technology General Chemistry Carbon nanotube 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Catalysis 0104 chemical sciences law.invention Solvent chemistry.chemical_compound Adsorption Aniline Polymerization chemistry law Materials Chemistry Absorption (chemistry) 0210 nano-technology Nuclear chemistry |
| Zdroj: | New Journal of Chemistry. 42:7030-7042 |
| ISSN: | 1369-9261 1144-0546 |
| DOI: | 10.1039/c8nj00861b |
| Popis: | In this study, a composite based on poly(aniline-co-pyrrole)/multi-walled carbon nanotubes, named poly(Ani-co-Py)/MWCNT, was synthesized by chemical oxidation polymerization in a triple-phase interface system and evaluated as an adsorbent for the removal of phenylbutazone (PBZ) from an aqueous solution. To compare and understand the whole process, poly(Ani-co-Py)/MWCNT and pristine MWCNT were studied using adsorption and kinetic models. These materials were characterized by FTIR, TGA and SEM. Further studies involving adsorption on poly(Ani-co-Py)/MWCNT were conducted at pH 6 and on pristine MWCNT at pH 2. Under these conditions, the materials exhibited adsorption of PBZ above 90%. Kinetic studies showed that the adsorption mechanism for the PBZ reached equilibrium at about 60 min, characterizing a rapid absorption, which showed that PBZ had no resistance in transferring the aqueous phase to the material surface. The equilibrium adsorption data were best fitted with the dual-site Langmuir–Freundlich isotherm, with maximum adsorption capacities of 159.9 and 41.25 mg g−1, and constants related to the affinity for the drug of 0.099 and 0.178 L g−1, for poly(Ani-co-Py)/MWCNT and pristine MWCNT, respectively. Although the MWCNT has been reported in literature as an excellent adsorbent of various analytes, the poly(Ani-co-Py)/MWCNT presented a higher capacity for the removal of PBZ from an aqueous solution and a lower value related to its affinity for PBZ. This will possibly make it most suitable as an adsorbent in the sample preparation process using a suitable solvent for subsequent determination. |
| Databáze: | OpenAIRE |
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