Reversible aqueous metathesis reactions for potential application in dynamic combinatorial chemistry

Autor:	Luke Hunter, Glenn C. Condie, Margaret M. Harding
Rok vydání:	2010
Předmět:	Aqueous solution Chemistry Organic Chemistry Drug Discovery Dynamic combinatorial chemistry Allyl compound Salt metathesis reaction Organic chemistry Ring-opening metathesis polymerisation Allyl Sulfide Biochemistry Chemical reaction Catalysis
Zdroj:	Tetrahedron Letters. 51:5064-5067
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2010.07.105
Popis:	Solutions of heterocycles having an allyl sulfide unit and simple alkenes in 50% t -BuOH/H 2 O undergo reversible olefin metathesis reactions with the second generation Hoveyda–Grubbs catalyst. The choice of functional groups is limited by competitive chelation of some heterocycles with the catalyst, and other stereoelectronic effects.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::56037be4862af1f4a86463905d874978 https://doi.org/10.1016/j.tetlet.2010.07.105 Zobrazit plný text záznamu Full Text from ScienceDirect