Core excitation and autoionising transitions from states of N2, by near threshold electron impact

Autor: G Dawber, S. E. Michelin, D.P. Almeida, G C King
Rok vydání: 2001
Předmět:
Zdroj: Chemical Physics. 269:159-165
ISSN: 0301-0104
DOI: 10.1016/s0301-0104(01)00371-8
Popis: The inner-shell excited states, (1 s ) −1 (2 pπ u ) 1,3 Π , of N 2 have been observed by electron impact excitation, as a function of electron incident energy via their decay, by electronic ejection, to an ionic state of the molecule. The relative cross-sections for the formation of the N 2 + ( X 2 Σ g ) final ionic state, via the decay of these triplet and singlet inner-shell excited states, are compared with predictions of a theoretical model based on the distorted-wave approximation. Results of the distorted-wave calculations for the integral cross-sections for the transitions leading to the triplet and the singlet excited states are also presented.
Databáze: OpenAIRE