Metal carbonyl-trifluorophosphine systems IX. Tetracarbonylnitrosylmanganese substitution

Autor:	Carl A. Udovich, Ronald J. Clark
Rok vydání:	1970
Předmět:	Chemistry Organic Chemistry Infrared spectroscopy Metal carbonyl Fluorine-19 NMR Biochemistry Spectral line Inorganic Chemistry Crystallography Yield (chemistry) Intramolecular force Materials Chemistry Organic chemistry Solvolysis Physical and Theoretical Chemistry Isomerization
Zdroj:	Journal of Organometallic Chemistry. 25:199-206
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)86220-8
Popis:	The compound Mn(NO)(CO)4 reacts with PF3 under thermal-high pressure conditions to yield all compositions of the type Mn(NO)(PF3)x(CO)4-x except x = 4. These compounds are separable by gas-liquid partition chromatography. The infrared spectra show clear evidence for more than one isomer within each composition. Solvolysis studies show that isomerization occurs among the compositional species and the chemistry of this system clearly indicates it to be an intramolecular process. Fluorine NMR gives time average spectra at room temperature showing that the intramolecular process is an extremely fast one.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::55c30865bdac6b18dc6d62f09b972c1d https://doi.org/10.1016/s0022-328x(00)86220-8 Zobrazit plný text záznamu