Enhancement of the conjugative electron-releasing power of the hydroxy-group shown by the kinetics of solvolysis of 2-bromo-4-dibromomethylphenol and of 2-bromo-4-dibromomethyl-anisole

Autor: Peter B. D. de la Mare, Paul A. Newman
Rok vydání: 1982
Předmět:
Zdroj: Tetrahedron Letters. 23:1305-1308
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87090-2
Popis: The relative rates and kinetic forms for the solvolyses of 2-bromo-4-dibromomethyl-phenol and its methyl ether lead to a new estimate (σ + = −1.6) of the electron-releasing power of the hydroxy-group.
Databáze: OpenAIRE