Synthesis of copolymer of 1,3-dioxan-2-one and 2-hydro-2-oxo-1,3,2-dioxaphosphorinane

Autor:	Bin Hu, Ren-Xi Zhuo, Chang-Lie Fan
Rok vydání:	1998
Předmět:	symbols.namesake Fourier transform Polymers and Plastics Polymerization Chemistry Chemical structure Polymer chemistry Copolymer symbols Reactivity (chemistry)
Zdroj:	Polymers for Advanced Technologies. 9:145-149
ISSN:	1099-1581 1042-7147
DOI:	10.1002/(sici)1099-1581(199802)9:2<145::aid-pat742>3.0.co;2-c
Popis:	A new type of copolymer was synthesized by ring-opening polymerization of 1,3-dioxan-2-one (TMC) and 2-hydro-2-oxo-1,3,2-dioxaphosphorinane (TMP) using (i-C4H9)3Al as the initiator. The chemical structure was characterized by 1H nuclear magnetic resonance and Fourier transform infrared. The respective reactivity ratios of TMC and TMP were determined using the Kelen–Tudos method. Conversion studies showed that the composition of the copolymer agree with the feed composition at high conversions. © 1998 John Wiley & Sons, Ltd.
Databáze:	OpenAIRE
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