Assignment of 13C NMR spectrum for blepharismin C based on biosynthetic studies

Autor:	Yoshinosuke Usuki, Yoshiyuki Uruma, Hideo Iio, Kei Sakamoto, Matsumi Doe, Kohei Takumi
Rok vydání:	2007
Předmět:	Blepharismin biology Stereochemistry Chemistry Blepharisma japonicum Sodium Organic Chemistry chemistry.chemical_element Carbon-13 NMR biology.organism_classification Biochemistry Pigment Polyketide visual_art Drug Discovery visual_art.visual_art_medium
Zdroj:	Tetrahedron. 63:5548-5553
ISSN:	0040-4020
DOI:	10.1016/j.tet.2007.04.015
Popis:	Blepharismins, toxic pigments of the ciliate Blepharisma japonicum, are polycyclic ring-condensed compounds. Assignment of 13C NMR signals for blepharismin C, a major constituent of blepharismins, was achieved by analyses of the HMQC, HMBC, and INADEQUATE spectra of 13C-enriched samples obtained by feeding experiments using sodium [1-13C], [2-13C], and [1,2-13C2]acetates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::55ae614de93cb2a1587cd23d41c27c7c https://doi.org/10.1016/j.tet.2007.04.015 Zobrazit plný text záznamu Full Text from ScienceDirect