Two novel 3D microporous heterometallic 3d–4f coordination frameworks with unique (7, 8)-connected topology: Synthesis, crystal structure and magnetic properties

Autor:	Wen-Jing Liu, Xiao-Ping Ye, Hai-Hong Mo, Yingliang Liu, Li-Mei Chang, Xia Zhao, Yue-Peng Cai, Shan-Tang Yue, Zhi-Qiang Wei
Rok vydání:	2012
Předmět:	Inorganic Chemistry Crystallography Materials science Zigzag Magnetism Materials Chemistry Hydrothermal synthesis Nanotechnology Microporous material Crystal structure Physical and Theoretical Chemistry Topology (chemistry) Topology synthesis
Zdroj:	Inorganic Chemistry Communications. 16:95-99
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2011.12.004
Popis:	Two new 3D 3d–4f heterometallic microporous metal-organic frameworks, named, [Ln 2 Ni(Himdc) 2 (aip) 2 (H 2 O) 4 ]·6H 2 O [Ln = Nd ( 1 ), La ( 2 ); H 3 imdc = imidazole-4,5-dicarboxy acid; aip = 5-aminoisophthalic acid], have been successfully synthesized through the reaction of Ln 2 O 3 , NiSO 4 ·6H 2 O, H 3 imdc, aip and H 2 O. Compounds 1 and 2 are isomorphic, displaying rare interesting 3D heterometallic networks with (7, 8)-connected topology based on the linkages of 2D layers and 1D zigzag chains. In addition, the magnetic properties of the two compounds have been investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5586147cdf50a05fb97bcfdd1e91db72 https://doi.org/10.1016/j.inoche.2011.12.004 Zobrazit plný text záznamu Full Text from ScienceDirect