Reactions of cyclic arsines with iron and manganese carbonyls

Autor:	Bruce O. West, Patricia S. Elmes
Rok vydání:	1971
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Organic Chemistry Inorganic chemistry Materials Chemistry Dimanganese decacarbonyl chemistry.chemical_element Manganese Physical and Theoretical Chemistry Biochemistry Arsenic Iron pentacarbonyl
Zdroj:	Journal of Organometallic Chemistry. 32:365-370
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(00)82647-9
Popis:	The cyclic arsines (AsCH3)5, (AsC2H5)5 and (AsC6H5)6 react with iron pentacarbonyl to yield products of general formula [Fe(CO)3]2(AsR)4. Dimanganese decacarbonyl and pentamethylcyclopentaarsine react in the presence of light at room temperature to give Mn2(CO)8(AsCH3)5 and at elevated temperatures to give [Mn(CO)3(AsCH3)4]2. Structures are proposed in which the MnMn bond of Mn2(CO)10 is replaced by bridging arsenic chains.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::557e537ecc4d6fccc853ddb3da7e23c3 https://doi.org/10.1016/s0022-328x(00)82647-9 Zobrazit plný text záznamu