Synthesis of Poly(3-alkylthienylene ketone)s by the Pd-Catalyzed Copolymerization of Carbon Monoxide with Thienyl Mercuric Chlorides

Autor:	M. David Curtis, Mark D. McClain
Rok vydání:	1996
Předmět:	chemistry.chemical_classification Ketone General Chemical Engineering General Chemistry Polymer Photochemistry Catalysis chemistry.chemical_compound chemistry Pyridine Polymer chemistry Materials Chemistry Copolymer Absorption (chemistry) Carbon monoxide
Zdroj:	Chemistry of Materials. 8:945-951
ISSN:	1520-5002 0897-4756
DOI:	10.1021/cm950590d
Popis:	Poly(thienylene ketone)s are formed by the copolymerization of bis(chloromercuri)thiophenes with carbon monoxide. The reaction is carried out in hot pyridine with a Pd catalyst under 500 psi of CO. The polymers, poly(3-methylthienylene ketone), poly(3-butylthienylene ketone), and poly(3-(carboethoxymethyl)thienylene ketone), with molecular weights, Mn, ranging from 1600 to 2700, were produced. The polymers have UV−vis absorption maxima near 360 nm, assigned to π−π* transitions, and are reduced irreversibly near −1.0 V vs SCE.
Databáze:	OpenAIRE
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