Trimethylsilylation of Mineral Silicates

Autor: B. R. Currell, J. R. Parsonage
Rok vydání: 1981
Předmět:
Zdroj: Journal of Macromolecular Science: Part A - Chemistry. 16:141-166
ISSN: 0022-233X
DOI: 10.1080/00222338108082045
Popis: The application of the technique of trimethylsilylation to mineral silicates is reviewed. Information can be obtained on the molecular size distribution of the silicate anions and also on the aluminium distribution in a silicate backbone. Examples of the use of trimethylsilylation in the structural determinations of silicates include examination of sodium silicates and their solutions, calcium silicates, various glasses, cements and concretes. Included within the review is a discussion of the attempts to prepare new polyorganosiloxane materials. Trimethylsilylation of certain micas, for example, give polyorganosiloxane fluids and greases; and attempts to physically and chemically modify the polyorganosiloxane products are also reviewed.
Databáze: OpenAIRE