π-Electronic Ion-Pairing Assemblies for Photoswitching Materials

Autor: Ryohei Yamakado, Yohei Haketa, Hiromitsu Maeda, Kazuki Urakawa
Rok vydání: 2020
Předmět:
Zdroj: Photosynergetic Responses in Molecules and Molecular Aggregates ISBN: 9789811554506
DOI: 10.1007/978-981-15-5451-3_18
Popis: Ion-pairing assemblies consisting of appropriately designed oppositely charged π-electronic systems give rise to various functional supramolecular assemblies including crystals and soft materials based on the anisotropic orientation of charged species through electrostatic and other weak noncovalent interactions. The introduction of photo-responsive moiety to the charged species facilitated the formation of photo-responsive ion-pairing assemblies, whose assembling modes were controlled by photoirradiation. Furthermore, pyrrole-based π-system–PtII complexes were designed and exhibited unique photo-induced excited-state dynamics.
Databáze: OpenAIRE