Effect of γ substitution on the X-ray emission spectra and electronic structure of iron(III) and cobalt(III) acetylacetonates
| Autor: | O.L. Shcheka, V.D. Yumatov, T.B. Emelina |
|---|---|
| Rok vydání: | 1994 |
| Předmět: |
Radiation
Substitution (logic) Inorganic chemistry X-ray chemistry.chemical_element Electronic structure Electron Condensed Matter Physics medicine.disease Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials chemistry Atomic orbital medicine Physical chemistry Emission spectrum Physical and Theoretical Chemistry Cobalt Spectroscopy Vapours |
| Zdroj: | Journal of Electron Spectroscopy and Related Phenomena. 70:83-88 |
| ISSN: | 0368-2048 |
| Popis: | The electron structure of Fe(acac) 3 and Co(acac) 3 and their γ-halogen substituted compounds has been investigated by using X-ray emission spectroscopy of the vapours. The experimental data are compared with the results of theoretical calculations (Xα-DV method). The effects of γ substitution in ligands on the X-ray emission fine structure and stabilization of occupied orbitals are discussed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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