Zur Stereochemie der Ringöffnung von trans-1,2-Diphenylcyclopropanen mit Quecksilber(II)salzen

Autor:	M. Weissenfels, Yu. S. Šabarov, A. Hantschmann, S. G. Bandaev
Rok vydání:	1980
Předmět:	Solvent Chemistry Stereochemistry Diastereomer Medicinal chemistry
Zdroj:	Journal für Praktische Chemie. 322:643-648
ISSN:	0021-8383
DOI:	10.1002/prac.19803220416
Popis:	Stereochemistry of Ring Opening of trans-1,2-Diphenylcyclopropanes by Mercury(II) salts Reaction of trans-1,2-diphenylcyclopropanes 1 and 2 with mercuric salts yields diastereomeric 1,2-diphenylpropanole derivatives. The ratio of erythro and threo diastereomers depends on the nature of substituents and solvent properties. A mechanism is proposed to explain the different product ratios.
Databáze:	OpenAIRE
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