The α-C–H BDE in tetralin
| Autor: | Paulo M. Nunes, Rui M. Borges dos Santos, José A. Martinho Simões |
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| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Journal of Thermal Analysis and Calorimetry. 100:381-384 |
| ISSN: | 1572-8943 1388-6150 |
| DOI: | 10.1007/s10973-009-0632-0 |
| Popis: | The α-C–H bond dissociation enthalpy (BDE) in tetralin (1,2,3,4-tetrahydronaphtalene) was determined using time-resolved photoacoustic calorimetry as 357.6 ± 5.4 kJ mol−1. This value is some 10 kJ mol−1 higher than the only previous experimental determination but in remarkably good agreement with the α-C–H BDEs in the structurally related compounds such as 1-butene, cyclohexene, and ethylbenzene. |
| Databáze: | OpenAIRE |
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