Visible light-mediated decarboxylative amination of indoline-2-carboxylic acids catalyzed by Rose Bengal

Autor:	Zhi Guan, Griffin M. Schroeder, Meng-Jie Zhang, Yan-Hong He
Rok vydání:	2016
Předmět:	010405 organic chemistry General Chemical Engineering Radical General Chemistry 010402 general chemistry Photochemistry 01 natural sciences 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry Indoline Rose bengal Photocatalysis Organic chemistry Amination Visible spectrum
Zdroj:	RSC Advances. 6:96693-96699
ISSN:	2046-2069
DOI:	10.1039/c6ra17524d
Popis:	A visible light-induced decarboxylative amination of indoline-2-carboxylic acids and azodicarboxylate esters has been developed, in which the oxidation of α-amino acids provides a versatile CO2-extrusion platform to generate α-aminoalkyl radicals. The corresponding products were obtained with yields of up to 72% catalyzed by a metal-free photocatalyst under mild conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::55040f9dd70db73cffdf40338d4df125 https://doi.org/10.1039/c6ra17524d Zobrazit plný text záznamu