A synthesis of micandrol-C a novel methylthiophenanthrenediol isolated from the trunkwood of Micandropsis scleroxylon

Autor:	Melvyn V. Sargent, Anna B. Zwicky
Rok vydání:	1990
Předmět:	chemistry.chemical_compound chemistry Stereochemistry Magnesium chemistry.chemical_element Organic chemistry Phenols Phenanthrene
Zdroj:	Journal of the Chemical Society, Perkin Transactions 1. :1713
ISSN:	1364-5463 0300-922X
DOI:	10.1039/p19900001713
Popis:	The structure of the unusual phenanthrene micandrol-C (7-methyl-1-methylthiophenanthrene-2,6-diol)(16), isolated from the trunkwood of the Amazonian tree, Micandropsis scleroxylon W. Rodr., is confirmed by synthesis. The key step involved the cyclization of a cis-2-chlorostilbene in the presence of activated magnesium.
Databáze:	OpenAIRE
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